An iron–oxygen intermediate formed during the catalytic cycle of cysteine dioxygenase† †Electronic supplementary information (ESI) available: Experimental and computational details. See DOI: 10.1039/c6cc03904a Click here for additional data file.

Persistent four-coordinate iron-centered radical stabilized by π-donation† †Electronic supplementary information (ESI) available: Experimental, crystallographic, computational details, and crystal data for 2, 4, 5 and 8. CCDC 1057111–1057113 and 1425703. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5sc02601f Click here for additional data file. Click here for additional data file.

Institute for Materials Chemistry and Kasugakoen, Kasuga, Fukuoka 816-8580, Ja Department of Chemistry, Graduate Schoo Sendai 980-8578, Japan Institute for Materials Chemistry and En Fukuoka 819-0395, Japan CREST, Japan Science and Technology Fukuoka 816-8580, Japan † Electronic supplementary informati crystallographic, computational details, a 1057111–1057113 and 1425703. For ESI other electro...

Generation of 1,2-azaboretidines via reduction of ADC borane adducts† †Electronic supplementary information (ESI) available: Experimental, crystallographic, and computational details. CCDC 1042591–1042594. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5sc01077b Click here for additional data file. Click here for additional data file.

Silica-supported isolated gallium sites as highly active, selective and stable propane dehydrogenation catalysts† †Electronic supplementary information (ESI) available: Experimental details, material characterization data, catalytic measurement details and crystallographic details. CCDC 1499756. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c6sc05178b Click here for additional data file. Click here for additional data file.

Substrate selectivity of an isolated enoyl reductase catalytic domain from an iterative highly reducing fungal polyketide synthase reveals key components of programming† †Electronic supplementary information (ESI) available: Details of all experimental and characterisation data. See DOI: 10.1039/c6sc03496a Click here for additional data file. Click here for additional data file. Click here for additional data file.

Formation of a C–C double bond from two aliphatic carbons. Multiple C–H activations in an iridium pincer complex† †Electronic supplementary information (ESI) available: Experimental details, characterization data, Cartesian coordinates, additional graphs and computational details. CCDC 1024127–1024129. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c4sc03839h Click here for additional data file. Click here for additional data file.